Benzene

CAS Number:71-43-2
Chemical Formula:C6H6
Synonyms:
Benzene, OMniSolv(R)
Benzene, PestiSolv(R)
Benzene, for spectroscopy
Appearance: Transparent Liquid
MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)

Product Details

maleic-anhydride.html">material/benzene.html">Benzene is a colorless, volatile, highly flammable liquid widely applied in the chemical industry and attracted great attention in the early development of organic chemistry. Thanks to its unique structure, benzene exhibits high stability and rarely undergoes addition reactions under normal conditions. Addition reactions of benzene usually demand high temperature, high pressure and special catalysts. The most frequent reactions of benzene are substitution reactions, in which one or more hydrogen atoms can be replaced by various atoms or atomic groups. Three major substitution reactions of benzene include alkylation, halogenation and nitration. During alkylation, one or more alkyl groups take the place of hydrogen atoms.Benzene

Parameters

PropertyValue
Melting point5.5 °C (lit.)
Boiling point80 °C (lit.)
density0.874 g/mL at 25 °C (lit.)
vapor density2.77 (vs air)
vapor pressure166 mm Hg ( 37.7 °C)
refractive indexn20/D 1.501(lit.)
Fp12 °F
storage temp.room temp
solubilityMiscible with alcohol, chloroform, dichloromethane, diethyl ether, acetone and acetic acid.
pka43(at 25℃)
formLiquid
colorAPHA: ≤10
OdorPaint-thinner-like odor detectable at 12 ppm
Relative polarity0.111
Odor Threshold2.7ppm
explosive limit1.4-8.0%(V)
Water Solubility0.18 g/100 mL
λmaxλ: 280 nm Amax: 1.0
λ: 290 nm Amax: 0.15
λ: 300 nm Amax: 0.06
λ: 330 nm Amax: 0.02
λ: 350-400 nm Amax: 0.01
Merck14,1066
BRN969212
Henry's Law Constant10.4 at 45.00 °C, 11.4 at 50.00 °C, 13.3 at 55.00 °C, 14.5 at 60.00 °C, 16.8 at 65.00 °C, 19.2 at 70.00 °C (static headspace-GC, Park et al., 2004)
Dielectric constant2.3(20℃)
Exposure limitsTLV-TWA 10 ppm (~32 mg/m3) (ACGIH and OSHA); ceiling 25 ppm (~80 mg/m3) (OSHA and MSHA); peak 50 ppm (~160 mg/m3)/10 min/8 h (OSHA); carcinogenicity: Suspected Human Carcinogen (ACGIH), Human Sufficient Evidence (IARC).
Stability:Stable. Substances to be avoided include strong oxidizing agents, sulfuric acid, nitric acid, halogens. Highly flammable.
InChIKeyUHOVQNZJYSORNB-UHFFFAOYSA-N
LogP2.130
Surface tension28.891mN/m at 293.15K
CAS DataBase Reference71-43-2(CAS DataBase Reference)
IARC1 (Vol. 29, Sup 7. 100F, 120) 2018
NIST Chemistry ReferenceBenzene(71-43-2)
EPA Substance Registry SystemBenzene (71-43-2)

Safety Information

ItemDetails
Hazard CodesF,T
Risk Statements45-46-11-36/38-48/23/24/25-65-39/23/24/25-23/24/25
Safety Statements53-45-36/37-16-7
RIDADRUN 1114 3/PG 2
OEBE
OELTWA: 0.1 ppm, STEL: 1 ppm
WGK Germany3
RTECSCY1400000
F3-10
Autoignition Temperature560 °C
TSCAYes
HS Code2902 20 00
HazardClass3
PackingGroupII
Hazardous Substances Data71-43-2(Hazardous Substances Data)
ToxicityLD50 orally in young adult rats: 3.8 ml/kg (Kimura)
IDLA500 ppm

Product Application of Benzene CAS#71-43-2
Benzene exists in distillates of coal and coal tar, as well as petroleum products like gasoline. It can also be detected in gases and leachates from landfills containing industrial waste, construction debris and gardening refuse. Trace levels of benzene, toluene, xylene and other volatile organic compounds have been detected in soil and groundwater near many municipal landfills. Studies have evaluated benzene exposure during operations such as removal, cleaning, pumping and testing of underground gasoline storage tanks. Average human exposure ranged from 0.43 to 3.84 ppm within 1.5 to 6 hours, and the maximum short‑term (15‑minute) exposure reached 9.14 ppm. Benzene is also present in tobacco smoke, which may increase the risk of inhalation exposure.

Benzene serves as a solvent for waxes, resins and oils; a paint remover; a thinner for lacquers; a raw material in manufacturing dyes, pharmaceuticals, varnishes and linoleum; and a fundamental feedstock for producing many organic compounds.
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