N,N-Dimethylaniline

CAS Number: 121-69-7
Chemical Formula: C8H11N
Synonyms: N,N-Dimethylphenylamine, N,N-DIMETHYLACETATE, N-ACETYLDIMETHYLAMINE
Appearance: Yellow Liquid
MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)

Products Description

N,N-dimethylaniline is a tertiary amine compound derived from aniline, in which both hydrogen atoms of the amino group are replaced by methyl groups. It is categorized as a dimethylaniline derivative and a representative tertiary amine substance.N,N-Dimethylaniline

Chemical Properties

ItemValue
Melting point1.5-2.5 °C (lit.)
Boiling point193-194 °C (lit.)
density0.956 g/mL at 25 °C (lit.)
vapor density3 (vs air)
vapor pressure2 mm Hg (25 °C)
refractive indexn20/D 1.557(lit.)
Fp158 °F
storage temp.Store below +30°C.
solubility1.2g/l
pka5.15(at 25℃)
formLiquid
colorClear yellow
PH7.4 (1.2g/l, H2O, 20℃)
Relative polarity0.179
explosive limit1.2-7%(V)
Water Solubility1 g/L (20 ºC)
Merck143,234
BRN507140
Henry's Law Constant4.98×10⁻⁶ atm·m³/mol at 20 °C (approximaleic-anhydride.html">mate - calculated from water solubility and vapor pressure)
Dielectric constant4.4
Exposure limitsNIOSH REL: TWA 5 ppm (25 mg/m³), STEL 10 ppm (50 mg/m³), IDLH 100 ppm; OSHA PEL: TWA 5 ppm; ACGIH TLV: TWA 5 ppm, STEL 10 ppm (adopted).
StabilityStable. Incompatible with strong oxidizing agents, strong acids, acid chlorides, acid anhydrides, chloroformates, halogens. Combustible.
InChIKeyJLTDJTHDQAWBAV-UHFFFAOYSA-N
LogP1.171 at 35℃
CAS DataBase Reference121-69-7(CAS DataBase Reference)
IARC3 (Vol. 57) 1993
NIST Chemistry ReferenceBenzenamine, N,N-dimethyl-(121-69-7)
EPA Substance Registry SystemN,N-Dimethylaniline (121-69-7)

Safety Information

ItemValue
Hazard CodesT,N
Risk Statements61-20/21-51/53-40-23/24/25
Safety Statements53-45-61-36/37-28A-28
RIDADRUN 2253 6.1/PG 2
OEBA
OELTWA: 5 ppm (25 mg/m³), STEL: 10 ppm (50 mg/m³) [skin]
WGK Germany3
RTECSBX4725000
F8
Autoignition Temperature370 °C DIN 51794
TSCAYes
HS Code2921 42 00
HazardClass6.1
PackingGroupII
Hazardous Substances Data121-69-7(Hazardous Substances Data)
ToxicityLD50 orally in rats: 1.41 ml/kg (Smyth)
IDLA100 ppm

Product Application

N,N-Dimethylaniline is widely used in the production of dyestuffs, and also acts as a solvent, a methylation reagent, and a curing agent for fiberglass-reinforced resins.
As an important dye intermediate, it is used in the synthesis of alkaline yellow, Crystal Violet 5BN, basic magenta green, basic lake blue BB, basic brilliant blue R, cationic red 2BL, brilliant red 5GN, violet 3BL, brilliant blue and other colorants. In the pharmaceutical industry, it is applied in the preparation of cefazolin V, sulfamonomethoxine, sulfadoxine, fluorocytosine and other active pharmaceutical ingredients. It also serves as an intermediate for vanillin, a stabilizer for colorimetric peroxidase assays, and a common reagent in organic synthesis.

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