Acrylic acid

Chemical Name: Acrylic acid

IUPAC Name: 2-Propenoic acid

Synonyms: Acroleic acid, Glacial acrylic acid

CAS Registry Number: 79-10-7

EC Number: 201-177-9

Molecular Formula: C₃H₄O₂

Molecular Weight: 72.06

Physical Appearance: Clear liquid

Standard Packaging: 200kg plastic drum, 1000L IBC tote, bulk ISO tank container

Sample Supply: Free samples available upon client request

MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)

Products Description of Acrylic AcidCAS#79-10-7
Product Grade: Industrial Grade

Minimum Purity: ≥99% (Tested by GC)

Visual Characteristic: Colorless transparent liquid with sharp, strong irritating odor

Melting Point: 13.5°C

Boiling Point: 141°C

Vapor Pressure: 0.4 kPa at 25°C

Relative Density: 1.0511 (20°C)

Refractive Index (20°C): 1.420–1.422

Closed Cup Flash Point: 48.5°C

Viscosity (20°C): 1.22 mPa·s

Solubility: Fully miscible with water in any proportion; soluble in ethanol, diethyl ether, chloroform and most polar organic solvents

Standard Stabilizer: 180–220 ppm MEHQ (Hydroquinone monomethyl ether) added to prevent spontaneous polymerization

Chemical Stability: Highly chemically active; prone to self-polymerization under high temperature, direct sunlight or oxygen-free environment

Incompatible Substances: Strong oxidizing agents, strong alkalis, all types of free-radical polymerization initiators

Storage Suggestion: Store in cool, shaded and ventilated warehouse with controlled temperature between 15–25°C; keep containers fully sealed and avoid long-term exposure to airAcrylic acid

Parameters

ParameterValue
Melting point13 °C (lit.)
Boiling point139 °C (lit.)
density1.051 g/mL at 25 °C (lit.)
vapor density2.5 (vs air)
vapor pressure4 mm Hg ( 20 °C)
refractive indexn20/D 1.421
Fp130 °F
storage temp.Store at +15°C to +25°C.
solubility1000g/l
formLiquid
pka4.25(at 25℃)
colorClear
OdorAcrid odor
PH Range1 - 2
PH3.68(1 mM solution);3.14(10 mM solution);2.63(100 mM solution);
explosive limit3.9-19.8%(V)
Water SolubilityMISCIBLE
SensitiveAir Sensitive
λmax231nm(lit.)
Merck14,130
BRN635743
Exposure limitsTLV-TWA 10 ppm (30 mg/m3) (ACGIH).
Stability:Stability Unstable - may contain p-methoxyphenol as an inhibitor. Prone to hazardous polymerization. Combustible. Incompatible with strong oxidizing agents, strong bases, amines. Contact with oxidizers may cause fire. Light and air sensitive. Hygroscopic.
Cosmetics Ingredients FunctionsNAIL CONDITIONING
LogP0.46 at 25℃
CAS DataBase Reference79-10-7(CAS DataBase Reference)
NIST Chemistry Reference2-Propenoic acid(79-10-7)
IARC3 (Vol. 19, Sup 7, 71) 1999
EPA Substance Registry SystemAcrylic acid (79-10-7)
ECETOC JACC REPORTAcrylic acid (79-10-7)

Safety Information

ItemDetails
Hazard CodesC,N
Risk Statements10-20/21/22-35-50
Safety Statements26-36/37/39-45-61
RIDADRUN 2218 8/PG 2
OEBB
OELTWA: 2 ppm (6 mg/m3) [skin]
WGK Germany1
RTECSAS4375000
F8-13
Autoignition Temperature744 °F
TSCAYes
HazardClass8
PackingGroupII
HS Code29161110
Hazardous Substances Data79-10-7(Hazardous Substances Data)
ToxicityLD50 orally in rats: 2.59 g/kg (Smyth)

Product Application of Acrylic acidCAS#79-10-7

Chemical Reactivity & Derivative Monomer Introduction

Acrylic acid carries typical carboxylic acid functional group and active carbon-carbon double bond, presenting diversified chemical reactivity. It can conduct esterification reactions with various alcohol substances to generate corresponding acrylic ester products.

All acrylic acid esters and their metal salt derivatives are uniformly named acrylates, also known as propenoates under systematic chemical nomenclature.

The mainstream alkyl acrylate monomers synthesized from acrylic acid raw material include methyl acrylate, ethyl acrylate, butyl acrylate and 2-ethylhexyl acrylate. These acrylate monomers are core intermediate raw materials widely used in water-based coatings, industrial adhesives, textile binders, superabsorbent polymers and printing ink manufacturing.


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FAQ

Q: What key risks and storage limits should we notice during acrylic acid storage and transportation?

A: Acrylic acid has two major hazards: strong corrosive irritation and auto-polymerization risk.

  1. Temperature control: Keep storage and transit temperature within 15–25°C; temperatures above 30°C will accelerate polymerization, while temperature below 13.5°C will cause crystallization and uneven distribution of stabilizer.
  2. Segregation rule: Strictly separate acrylic acid from strong oxidants and strong alkaline chemicals to avoid violent chemical reactions.
  3. Container requirement: All sealed packaging must retain proper MEHQ inhibitor content and partial dissolved oxygen to inhibit runaway polymerization during long-term storage.

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