Tolylene-2,4-diisocyanate

CAS Number: 584-84-9
Chemical Formula: C9H6N2O2
Synonyms:
1,3-Diisocyanato-4-Methylbenzene
2,4-Toluylene Diisocyanate
Tolylene-2,4-diisocyanate 95%;
Appearance: Colorless liquid
HS Code: 29291010
MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)

Products Description of Tolylene-2,4-diisocyanate CAS#maleic-anhydride.html">material/tolylene-2-4-diisocyanate.html">584-84-9
Toluene diisocyanate (TDI), with the molecular formula (OCN)2C6H3CH3, is a water-white to pale-yellow liquid featuring a strong, pungent odor. It reacts with water to release carbon dioxide. It has a specific gravity of 1.22, making it denser than water. TDI is toxic through inhalation and ingestion and is a severe irritant to skin, eyes, and other tissues. The TLV in air is 0.005 ppm, and the IDLH level is 10 ppm.Tolylene-2,4-diisocyanate

Parameters

ItemValue
Melting point20-22 °C(lit.)
Boiling point124-126 °C18 mm Hg(lit.)
density1.225 g/mL at 25 °C
vapor density6 (vs air)
vapor pressure0.03 mm Hg ( 25 °C)
refractive indexn20/D 1.568(lit.)
Fp250 °F
storage temp.2-8°C
solubilityMiscible with ether, acetone, benzene, carbontetrachloride and chlorobenzene.
formLiquid
Specific Gravity1.225
colorColorless
OdorSharp, pungent odor detectable at 0.02 to 0.4 ppm
explosive limit9.5%
Water Solubilityreacts
SensitiveMoisture Sensitive
Merck14,9530
BRN744602
Exposure limitsTLV-TWA 0.0355 mg/m3 (0.005 ppm) (ACGIH and NIOSH); STEL or ceiling/10 min 0.142 mg/m3 (0.02 ppm) (ACGIH, NIOSH, and OSHA); IDLH 71 mg/m3 (10 ppm) (NIOSH).
Stability:Stable, but decomposes in the presence of moisture. Also heat and light sensitive. Readily polymerizes in contact with base. Reacts with compounds containing active hydrogen. Incompatible with strong oxidizing agents. Corrodes some copper and aluminium alloys.
InChIKeyDVKJHBMWWAPEIU-UHFFFAOYSA-N
LogP3.43 at 22℃
CAS DataBase Reference584-84-9(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 2,4-diisocyanato-1-methyl-(584-84-9)
EPA Substance Registry SystemToluene-2,4-diisocyanate (584-84-9)

Safety Information

ItemValue
Hazard CodesT+
Risk Statements26-36/37/38-40-42/43-52/53
Safety Statements23-36/37-45-61
RIDADRUN 2078 6.1/PG 2
WGK Germany2
RTECSCZ6300000
F10-21
Autoignition Temperature>619 °C
TSCAYes
HazardClass6.1
PackingGroupII
HS Code29291010
Hazardous Substances Data584-84-9(Hazardous Substances Data)
ToxicityAcute oral LD50 for rats 5,800 mg/kg, wild birds 100 mg/kg (quoted, RTECS, 1985).
IDLA2.5 ppm

Product Application of Tolylene-2,4-diisocyanate CAS#584-84-9
Toluene-2,4-diisocyanate is among the most widely used isocyanate materials. It is widely applied in manufacturing rigid and flexible urethane foams, elastomers, and coatings. Besides being used as a pure compound, it is commercially available as mixtures of 2,4- and 2,6-isomers at ratios of 80:20 and 65:35. Occupational allergy is the main cause of work-related respiratory diseases worldwide. Toluene-2,4-diisocyanate (TDI) is one of the most common respiratory sensitizers causing occupational asthma.
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