Citric acid monohydrate

Chemical Name: Citric acid monohydrate

Synonyms: Monohydrous Citric Acid, 2-hydroxy-1,2,3-propanetricarboxylic acid monohydrate

CAS Registry Number: 5949-29-1

EINECS No.: 201-069-1

Molecular Formula: C₆H₁₀O₈

Molecular Weight: 210.1388

Appearance: Uniform white crystalline solid / white crystalline powder

Sample Support: Samples are available for quality testing

MOQ (Minimum Order Quantity): 1 Full Container Load (FCL) for bulk export orders

Standard Export Packing: 25kg kraft paper bag lined with PE plastic film; IBC tote bulk packing for large-volume demands

Basic Storage Requirement: Seal tightly and store in cool, dry and well-ventilated warehouse, avoid direct sunlight

Products Description of Citric acid monohydrate CAS#5949-29-1

Industrial-grade citric acid monohydrate features a minimum purity of 99.5%. It is an odorless white crystalline powder with combustible dust properties.

Melting Point: 135–152℃

Boiling Point: 309.6℃ (decomposes at high temperature)

Vapor Pressure: Less than 1 Pa at 25℃

Relative Density (20℃, water=1): 1.54

Water Solubility: 1630g per liter at 20℃, dissolves rapidly in cold and hot water

Organic Solvent Solubility: Freely soluble in ethanol, slightly soluble in diethyl ether

Flash Point: 173.9℃

Chemical Stability: Stable under normal ambient storage conditions; the crystal will effloresce gradually in dry air.

Chemical Incompatibility: Must be isolated and kept far away from strong oxidizing agents to prevent unwanted chemical reactions.

Extra Quality Control Index: Heavy metal content (Lead, Arsenic, Mercury) complies with international industrial raw material standards, with low impurity residue.

Citric acid monohydrate

Parameters

PropertyValue
Melting point135 °C
Boiling point56 °C760 mm Hg(lit.)
bulk density800-1000kg/m3
density0.791 g/mL at 25 °C(lit.)
vapor density2 (vs air)
vapor pressure184 mm Hg ( 20 °C)
refractive indexn20/D 1.359(lit.)
Fp1 °F
storage temp.no restrictions.
solubilityCitric Acid Monohydrate is very soluble in water, freely soluble in ethanol and sparingly soluble in ether.
pka3.138, 4.76, 6.401
formSolid
colorWhite
Specific Gravity0.810 (20/4℃)
OdorTypical, practically odorless
PH1.85 (50g/l, H2O, 25℃)
Water Solubility1630 g/L (20 oC) ;H2O: soluble 54% (w/w) at 10°C (Citric acid in water)
SensitiveHygroscopic
Merck14,2326
BRN4018641
Stability:Stable. Incompatible with oxidizing agents, bases, reducing agents, nitrates.
InChIKeyYASYEJJMZJALEJ-UHFFFAOYSA-N
CAS DataBase Reference5949-29-1(CAS DataBase Reference)
NIST Chemistry ReferenceCitric acid monohydrate(5949-29-1)
EPA Substance Registry System1,2,3-Propanetricarboxylic acid, 2-hydroxy-, hydrate (1:1) (5949-29-1)

Safety Information

ItemValue
Hazard CodesF,Xi
Risk Statements11-36-66-67-41-36/37/38-37/38
Safety Statements9-16-26-37/39-36/37/39-36
RIDADRUN 1090 3/PG 2
WGK Germany1
RTECSAL3150000
TSCAYes
HS Code29181400
ToxicityLD50 orally in Rabbit: 3000 mg/kg

Product Application of Citric acid monohydrate CAS#5949-29-1
 

Multi-Scenario Industrial Application Introduction

Citric acid monohydrate is a natural tricarboxylic acid originally extracted from citrus fruits, with versatile functional properties including antioxidation, pH adjustment, chelation and antisepsis, widely applied in pharmaceutical and food processing industries:

Pharmaceutical Industry Usage

It acts as a core pharmaceutical excipient with prominent antioxidant activity. It can effectively stabilize and protect active pharmaceutical ingredients, and serves as a mild preservative to extend the shelf life of medicinal preparations. As a professional pH adjuster, it regulates the acid-base balance of oral syrups, effervescent tablets and ointment formulations. Besides, it can chelate calcium ions in blood samples, functioning as an anticoagulant reagent for clinical blood testing.

Food & Beverage Industry Usage

It is a mainstream food additive and food-grade acidulant for drinks, candies, canned food and dairy products. It can enhance sour flavor, inhibit microbial reproduction and preserve food freshness. Meanwhile, it works as an efficient synergist when mixed with composite antioxidants, greatly improving the anti-oxidation effect of food formulas.

Supplementary Minor Application

It can also be used as chelating agent and pH regulator in daily chemical cleaning products and cosmetic raw material formulations.

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