Maleic anhydride CAS 108-31-6

Chemical Full Name: Maleic Anhydride

Abbreviation: MA

CAS Registry Number: 108-31-6

Synonyms: 2,5-Furandione, cis-Butenedioic anhydride

Molecular Formula: C₄H₂O₃

Molecular Weight: 98.06

Appearance: Orthorhombic colorless needle-shaped or flake crystals; white solid under normal temperature with a sharp acidic irritating odor

HS Customs Code: 2917 14 00

UN Hazard Code: UN2215

Industrial Purity Standard: ≥99.7%

Melting Color (Hazen): ≤8

Residue on Ignition: Undetectable

MOQ (Minimum Order Quantity): 1 Full Container Load (1 FCL)

Sample Service: Laboratory test samples are available; customers only bear the freight cost

Standard Packaging: 25kg PE-lined woven bags, 1000kg bulk IBC totes

Products Description of Maleic anhydride CAS# 108-31-6
 

Maleic anhydride is the cyclic anhydride derived from maleic acid, with stable crystalline morphology recrystallized from chloroform or diethyl ether to form neat needle crystals.

  • Melting Point: 60 ℃
  • Boiling Point: 82 ℃ under 1.8665 kPa vacuum condition
  • Relative Density: 1.3146 (60 ℃)
  • Vapor Pressure: 0.2 mmHg at 20 ℃
  • Solubility Performance: Fully soluble in acetone, chloroform and diethyl ether; slightly soluble in petroleum ether; reacts rapidly with water
  • Core Chemical Reactivity

    1. Hydrolysis: Undergoes hydrolysis with water to generate maleic acid
    2. Esterification: Reacts with various alcohols to produce corresponding maleate ester derivatives
    3. Diels-Alder cycloaddition: Highly reactive with conjugated dienes to form cyclic adducts
  • Chemical Stability: Stable under sealed, cool and dry storage conditions; strictly incompatible with water, strong oxidants, strong alkalis, amines and active metals
  • Safety Hazard Property: Classified as toxic corrosive hazardous chemical; causes severe irritation and damage to human eyes, skin and respiratory mucous membranes; GHS hazard label marked with Danger signal word

Maleic anhydride

Parameters

ParameterValue
Melting point51-56 °C (lit.)
Boiling point200 °C (lit.)
density1.48
bulk density700-800kg/m3
vapor density3.4 (vs air)
vapor pressure0.16 mm Hg ( 20 °C)
refractive index1.4688 (estimate)
Fp218 °F
storage temp.Store below +30°C.
solubilityChloroform (Slightly), Ethyl Acetate (Slightly)
pka0[at 20 ℃]
formpowder
colorWhite
PH0.8 (550g/l, H2O, 20℃)Hydrolysis
OdorMild acrid odor.
explosive limit1.4-7.1%(V)
Water Solubility79 g/100 mL (25 ºC)
SensitiveMoisture Sensitive
Merck14,5704
BRN106909
Henry's Law Constant(atm·m³/mol): Not applicable - reacts with water
Exposure limitsNIOSH REL: TWA 1 ppm (0.25 mg/m³ ), IDLH 10 ppm; OSHA PEL: TWA 0.25 ppm; ACGIH TLV: TWA 0.25 ppm with an intended change of 0.1 ppm.
Dielectric constant51.0(60℃)
StabilityStable. Combustible. Incompatible with water, strong oxidizing agents, alkali metals, strong bases, amines, most common metals, polymerization catalysts and accelerators.
InChIKeyFPYJFEHAWHCUMM-UHFFFAOYSA-N
LogP-2.61 at 20℃
CAS DataBase Reference108-31-6(CAS DataBase Reference)
NIST Chemistry Reference2,5-Furandione(108-31-6)
EPA Substance Registry SystemMaleic anhydride (108-31-6)

Safety Information

ItemDetails
Hazard CodesC
Risk Statements22-34-42/43
Safety Statements22-26-36/37/39-45
OEBC
OELTWA: 1 mg/m3 (0.25 ppm)
RIDADRUN 2215 8/PG 3
WGK Germany1
RTECSON3675000
F21
Autoignition Temperature870 °F
TSCAYes
HS Code2917 14 00
HazardClass8
PackingGroupIII
Hazardous Substances Data108-31-6(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 1090 mg/kg LD50 dermal Rabbit 2620 mg/kg
IDLA10 mg/m3

Product Application of Maleic anhydride CAS# 108-31-6
 

Maleic anhydride acts as a fundamental organic chemical intermediate with cross-industry applications covering resin manufacturing, fine chemicals, pharmaceutical & agrochemical sectors:

  1. Synthetic Resin Industry

    Core raw material for producing unsaturated polyester resin and alkyd resin; key feedstock to synthesize downstream chemical products including 1,4-butanediol, γ-butyrolactone, tetrahydrofuran and succinic acid

  2. Pharmaceutical & Pesticide Manufacturing

    Indispensable intermediate for the synthesis of multiple pharmaceutical active pharmaceutical ingredients (APIs) and pesticide active components

  3. Fine Chemical Auxiliary Industry

    Applied in paper sizing agents, paint modifiers, lubricant oil additives, water treatment scale inhibitors, plastic processing aids and copolymer monomer production

  4. Other Scenarios

    Raw material for food-grade oil preservatives, ink additives, fumaric acid and tartaric acid synthesis

Factory and Equipment Show
Fast delivery time
Inventory 2-3 working days New production 7-10 working days

FAQ

Q1: Are you a maleic anhydride manufacturer or a trading company? Can I check your official website?

A: We are an integrated manufacturing and trading chemical enterprise with self-owned standardized production workshops and independent quality inspection laboratories. Our official website is https://www.hlhschem.com. We adopt direct factory supply mode with zero intermediate links, which effectively reduces customers’ procurement costs while maintaining stable product purity and continuous mass supply capacity. We also support customized packaging solutions and full-set export certification documents for global customers.

Q2: Can I get test samples before bulk order? What is your minimum order quantity?

A: Sample service of maleic anhydride is available for clients to test quality and performance in advance. Our formal bulk shipment MOQ is 1 full container load (1 FCL). We maintain year-round sufficient spot inventory to guarantee fast delivery after order confirmation, and our technical team can provide professional MSDS and technical parameter guidance for all inquiries.

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