Maleic anhydride CAS# 108-31-6

CAS Registry Number: 108-31-6

Chemical Name: Maleic Anhydride

Common Abbreviation: MAN

Molecular Formula: C₄H₂O₃

Molecular Weight: 98.06

Synonyms: Toxilic Anhydride, 2,5-Furandione, Maleic Anhydride

Appearance: Colorless or white crystalline powder with a characteristic pungent odor

Sample Availability: Available

MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)

Product Details

maleic-anhydride-cas-108-31-6.html">Maleic anhydride is the cyclic anhydride derived from maleic acid. It features excellent chemical activity due to its special molecular structure.

  • Melting Point: 52.8 °C
  • Boiling Point: 202 °C
  • Relative Density: 1.480 (20 °C)
  • Solubility: Soluble in acetone, ethanol, ether, benzene and other common organic solvents; undergoes hydrolysis when exposed to water to form maleic acid
  • Volatility: Moderately volatile at room temperature
  • Stability: Stable under normal ambient conditions; incompatible with strong bases, strong oxidants, amines and alcohols, and prone to chemical reactions or polymerization

Maleic anhydride

Maleic anhydride Chemical Properties

ItemValue
Melting point51-56 °C lit.
Boiling point200 °C lit.
bulk density700-800kg/m3
density1.48
vapor density3.4 vs air
vapor pressure0.16 mm Hg 20 °C
refractive index1.4688 estimate
Fp218 °F
storage temp.Store below +30°C.
solubilityChloroform Slightly Ethyl Acetate Slightly
formpowder
pka0 at 20 ℃
colorWhite
OdorMild acrid odor.
PH0.8 550g/l H2O 20℃ Hydrolysis
explosive limit1.4-7.1% V
Water Solubility79 g/100 mL 25 ºC
SensitiveMoisture Sensitive
Merck14,5704
BRN106909
Henry's Law Constantatm m3/mol Not applicable reacts with water
Exposure limitsNIOSH REL TWA 1 ppm 0.25 mg/m3 IDLH 10 ppm OSHA PEL TWA 0.25 ppm ACGIH TLV TWA 0.25 ppm with an intended change of 0.1 ppm.
Dielectric constant51.0 60℃
StabilityStable Combustible Incompatible with water strong oxidizing agents alkali metals strong bases amines most common metals polymerization catalysts and accelerators.
Cosmetics Ingredients FunctionsFILM FORMING
InChI1S/C4H2O3/c5-3-1-2-4 6 7-3/h1-2H
InChIKeyFPYJFEHAWHCUMM-UHFFFAOYSA-N
SMILESO=C1OC O C=C1
LogP-2.61 at 20℃
CAS DataBase Reference108-31-6 CAS DataBase Reference
NIST Chemistry Reference2,5-Furandione 108-31-6
EPA Substance Registry SystemMaleic anhydride 108-31-6

Safety Information

ItemValue
Hazard CodesC
Risk Statements22-34-42/43
Safety Statements22-26-36/37/39-45
RIDADRUN 2215 8 PG 3
OEBC
OELTWA 1 mg/m3 0.25 ppm
WGK Germany1
RTECSON3675000
F21
Autoignition Temperature870 °F
TSCATSCA listed
HS Code2917 14 00
HazardClass8
PackingGroupIII
Storage Class6.1D Non-combustible acute toxic Cat.3 toxic hazardous materials or hazardous materials causing chronic effects
Hazard ClassificationsAcute Tox 4 Oral Eye Dam 1 Resp Sens 1 Skin Corr 1B Skin Sens 1A STOT RE 1 Inhalation
Hazardous Substances Data108-31-6 Hazardous Substances Data
ToxicityLD50 orally in Rabbit 1090 mg/kg LD50 dermal Rabbit 2620 mg/kg
IDLA10 mg/m3

Product Application Of Maleic anhydride CAS#108-31-6

This compound possesses two highly active reactive sites in its molecular structure, which endows it with superior reactivity and versatile performance in organic synthesis and industrial production. It is widely recognized as a fundamental and high-value organic chemical raw material across multiple industries.

Main Applications

  1. Organic Synthesis & Chemical Reactions

    It is commonly used as a typical dienophile in Diels-Alder reactions, serving as a key intermediate for various fine chemical syntheses.

  2. Agrochemical Industry

    Applied in the production of a variety of agrochemical products, including maleic hydrazide, malathion and other pesticides and plant growth regulators.

  3. Pharmaceutical & Dye Industry

    Acts as an important intermediate for the synthesis of pharmaceutical compounds and dyestuff raw materials.

  4. Resin & Polymer Industry

    Widely adopted in the manufacturing of multiple resin products and participates in various copolymerization processes. It is an essential raw material for unsaturated polyester resins, alkyd resins, plasticizers, adhesives, coatings and polymer modifiers, greatly improving the mechanical strength, weather resistance and processing performance of finished polymer products.

 

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