Vinyl acetate

CAS Number: 108-05-4
Chemical Formula: C4H6O2
Synonyms: Vinyl acetate, Acetoxyethylene, Acetic acid vinyl
Appearance: Colorless liquid
HS Code: 29153200
MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)

Products Description of Vinyl acetatemaleic-anhydride.html">material/vinyl-acetate.html">CAS# 108-05-4

Colorless flammable liquid with a sweet ether-like odor. Miscible with ethanol, soluble in ether, acetone, chloroform, carbon tetrachloride and other organic solvents, but insoluble in water.

Vinyl acetate

Parameters

ParameterValue
Melting point-93 °C (lit.)
Boiling point72-73 °C (lit.)
density0.934 g/mL at 25 °C (lit.)
vapor density3 (vs air)
vapor pressure88 mm Hg (20 °C)
refractive indexn 20/D 1.395(lit.)
Fp20 °F
storage temp.2-8°C
solubility20g/l
formLiquid
colorClear colorless to almost colorless
PH7 (20g/l, H2O, 20℃)
OdorSweet, pleasant, fruity
explosive limit2.6-13.4%(V)
Water Solubility23 g/L (20 ºC)
SensitiveLight Sensitive
Merck14,9992
BRN1209327
Henry's Law Constant4.81 (calculated, Howard, 1989)
Exposure limitsNIOSH REL: 15-min ceiling 4 ppm (15 mg/m³); ACGIH TLV: TWA 10 ppm, STEL 15 ppm (adopted).
Dielectric constant4.5(23℃)
StabilityStable. Highly flammable. Incompatible with acids, bases, oxidizing agents, peroxides, chlorosulfonic acid, ethylene imine, hydrochloric acid, oleum, nitric acid, sulfuric acid, 2-aminoethanol, light. Susceptible to polymerization; commercial product may be trichloroethylene.html">stabilized by the addition of hydroquinone.
LogP0.73 at 20℃
Surface tension22.476mN/m at 298.15K
CAS DataBase Reference108-05-4(CAS DataBase Reference)
NIST Chemistry ReferenceAcetic acid ethenyl ester(108-05-4)
IARC2B (Vol. Sup 7, 63) 1995
EPA Substance Registry SystemVinyl acetate (108-05-4)

Safety Information

ItemDetails
Hazard CodesF,T,Xn
Risk Statements11-39/23/24/25-23/24/25-36-20/21/22-40-37-20
Safety Statements16-23-29-33-45-36/37-7-9
OELCeiling: 4 ppm (15 mg/m3) [15-minute]
RIDADRUN 1301 3/PG 2
WGK Germany2
RTECSAK0875000
Autoignition Temperature801 °F
TSCAYes
HazardClass3
PackingGroupII
HS Code29153200
HS Code29333999
Hazardous Substances Data108-05-4(Hazardous Substances Data)
ToxicityLD50 orally in rats: 2.92 g/kg (Smyth, Carpenter)

Product Application of Vinyl acetate CAS# 108-05-4

Vinyl acetate serves as a key raw material for producing vinylon synthetic fiber. It can be homopolymerized or copolymerized with other monomers to form polyvinyl alcohol, vinyl acetate-ethylene copolymer (EVA), vinyl acetate-vinyl chloride copolymer (EVC), vinyl acetate-acrylonitrile fiber, and vinyl acetate-acrylate copolymer. These products are widely used in adhesives, architectural coatings, textile sizing and finishing agents, paper reinforcing agents, and safety glass manufacturing. Vinyl acetate also reacts with ethanol and bromine to yield bromoacetaldehyde diethyl acetal, an intermediate for the pharmaceutical methimazole.

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