Methyl cinnamate

CAS Number: 103-26-4
Chemical Formula: C10H10O2
Synonyms:
METHYL 3-PHENYLPROPENOATE
METHYL TRANS-3-PHENYLACRYLATE
METHYL TRANS-3-PHENYLPROPENOAT
Appearance: Transparent Liquid
MOQ (Minimum Order Quantity): 1 FCL Full Container Load

Product Details

Methyl cinnamaleic-anhydride.html">mate CAS#103-26-4
Methyl cinnamate presents as white to pale yellow crystals with a characteristic cherry and balsamic fragrance. It has a melting point around 34 °C, boiling point at 260 °C, refractive index nD20 of 1.5670, and relative density d435 of 1.0700. It dissolves in alcohol, ether, glycerol.html">glycerin, propylene glycol, most non-volatile oils and mineral oils, while being insoluble in water.
Naturally, it can be found in basil oil (content up to 52%), galangal oil, and laurel leaf oil.Methyl cinnamate

Parameters

ItemValue
Melting point33-38 °C (lit.)
Boiling point260-262 °C (lit.)
density1.092
vapor pressure0.73Pa at 25℃
refractive index1.5771
FEMA2698 | METHYL CINNAMATE
Fp>230 °F
storage temp.Sealed in dry,Room Temperature
solubilityChloroform (Slightly), Methanol (Slightly), soluble in alcohol, Propylene glycol, Mineral oil and oils.
formFused Crystalline Mass
colorWhite to light yellow
Specific Gravity1.092
Odorat 100.00 %. sweet balsam strawberry cherry cinnamon
Odor Typebalsamic
Water Solubilityinsoluble
Merck14,2299
JECFA Number658
BRN386468
Cosmetics Ingredients FunctionsPERFUMING
InChI1S/C10H10O2/c1-12-10(11)8-7-9-5-3-2-4-6-9/h2-8H,1H3/b8-7+
InChIKeyCCRCUPLGCSFEDV-BQYQJAHWSA-N
SMILESCOC(=O)\C=C\c1ccccc1
LogP2.68 at 25℃
CAS DataBase Reference103-26-4(CAS DataBase Reference)
NIST Chemistry Reference2-Propenoic acid, 3-phenyl-, methyl ester(103-26-4)
EPA Substance Registry SystemMethyl cinnamate (103-26-4)

Safety Information

ItemValue
Safety Statements22-24/25
WGK Germany1
RTECSGE0190000
TSCATSCA listed
HS Code29163990
Storage Class11 - Combustible Solids
Hazard ClassificationsSkin Sens. 1
ToxicityModerately toxic by ingestion . The oral LD50 for rats is 2610 mg / kg . It is combustible as a liquid, and when heated to decomposition it emits acrid smoke and irritating fumes.

Product Application

Methyl cinnamate is the methyl ester of cinnamic acid. It appears as a white or transparent solid with a powerful aromatic scent. It exists naturally in many plants, fruits such as strawberries, and culinary spices including Sichuan pepper and certain types of basil. Eucalyptus olida contains the highest known level of methyl cinnamate, reaching 98%, with a fresh weight yield of 2–6% in leaves and twigs.
It is widely used in flavor and fragrance manufacturing. Its taste is fruity similar to strawberry, and its aroma is sweet, balsamic, and fruity, evoking notes of cinnamon and strawberry.
It is known to attract male orchid bees such as Aglae caerulea.
Methyl cinnamate crystals can be extracted from Eucalyptus olida via steam distillation.

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