Naphthalene

CAS Number: 91-20-3
Chemical Formula: C10H8
Synonyms:
NAPHTHALENE WHITE, PURE
Naphthalene, refined
Appearance: Colorless and shiny monoclinic crystal
HS Code: 29029010
MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)

Products Description of Naphthalene CAS# 91-20-3
Naphthalene is the simplest fused aromaleic-anhydride.html">matic hydrocarbon made up of two benzene rings, often called mothballs. It ranks among the primary products from coal tar processing. Industrially, naphthalene exists as crude naphthalene (industrial naphthalene and pressed naphthalene) and refined naphthalene. Its molecular formula is C10H8 with a molar mass of 128.17. Key physical properties include a melting point of 80.28°C, solid density of 1.145 g/cm³, liquid density (85°C) of 0.9752 g/cm³, specific heat capacity (100°C) of 1809 J/(kg·K), and refractive index (85°C) of 1.5898. Naphthalene forms colorless monoclinic crystals that are volatile and sublimable, with a distinctive odor. It is flammable and can form explosive mixtures with air. Its petroleum ether solution emits a reddish-purple fluorescence under a mercury lamp. It is nearly insoluble in water but dissolves in diethyl ether, ethanol, benzene, and other solvents. Inhalation or skin absorption of naphthalene vapor or dust may lead to poisoning; the permissible exposure limit in air is 20 mg/m³. Naphthalene serves as a fundamental raw material for dyes, plastics, coatings, pharmaceuticals, pesticides, and related industries. It was once widely used directly as mothballs for protecting clothing and furs.Naphthalene

Parameters

ItemValue
Melting point80-82 °C (lit.)
Boiling point218 °C (lit.)
density0.99
bulk density550-600mg/m3
vapor density4.4 (vs air)
vapor pressure0.03 mm Hg ( 25 °C)
refractive index1.5821
Fp174 °F
storage temp.Store below +30°C.
solubilitymethanol: soluble50mg/mL, clear, colorless
formFaint beige to brown to salmon red powder
colorWhite to almost white
Specific Gravity1.145
Odorat 10.00 % in benzyl benzoate. pungent dry tarry
Odor Typepungent
explosive limit0.9-5.9%(V)
Water Solubility30 mg/L (25 ºC)
Merck14,6370
BRN142131
Henry's Law Constant5.64 at 25 °C (thermodynamic method-GC/UV spectrophotometry, Altschuh et al., 1999)
Exposure limitsTLV-TWA 10 ppm (~50 mg/m^{3}) (ACGIH, MSHA, and OSHA); STEL 15 ppm (~75 mg/m^{3}) (ACGIH); IDLH 500 ppm.
Dielectric constant2.5(85℃)
InChIKeyUFWIBTONFRDIAS-UHFFFAOYSA-N
LogP3.7 at 25℃
CAS DataBase Reference91-20-3(CAS DataBase Reference)
IARC2B (Vol. 82) 2002
NIST Chemistry ReferenceNaphthalene(91-20-3)
EPA Substance Registry SystemNaphthalene (91-20-3)

Safety Information

ItemValue
Hazard CodesXn,N,F,T
Risk Statements22-40-50/53-67-65-38-11-39/23/24/25-23/24/25-52/53-20
Safety Statements36/37-46-60-61-62-45-16-7-33-25-9
RIDADRUN 1334 4.1/PG 3
OEBA
OELTWA: 10 ppm (50 mg/m3), STEL: 15 ppm (75 mg/m3)
WGK Germany3
RTECSQJ0525000
Autoignition Temperature978 °F
TSCAYes
HazardClass4.1
PackingGroupIII
HS Code29029010
Hazardous Substances Data91-20-3(Hazardous Substances Data)
ToxicityAcute oral LD_{50} for guinea pigs 1,200 mg/kg, mice 533 mg/kg, rats 1,250 mg/kg (quoted, RTECS, 1985).
IDLA250 ppm

Product Application of Naphthalene CAS# 91-20-3
It is mainly employed in manufacturing phthalic anhydride and also acts as a raw material for producing dyes, pharmaceuticals, and other chemical products.

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